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The model-aided cathode design for lithium ion batteries is presented, which enables a systematically minimization of loss processes and an increase of power and energy density. The cathode model is parametrized without values from literature by combining microstructure analysis via FIB/SEM tomography and electrochemical impedance spectroscopy and finally validated.
microstructure --- modeling --- Mikrostruktur --- Elektromobilität --- Impedanz --- impedance --- Kathode --- cathode --- lithium-ion battery --- Lithium-Ionen Batterie --- microstructure --- modeling --- Mikrostruktur --- Elektromobilität --- Impedanz --- impedance --- Kathode --- cathode --- lithium-ion battery --- Lithium-Ionen Batterie
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Conversion-type electrodes are promising electrode materials for future lithium ion batteries since they exhibit high specific capacities compared to intercalation-type eclectrodes. In this work, a thermodynamic approach was used to elucidate the electrochemical behavior of conversion-type electrodes using Li-Cu-O and Li-Fe-O as model material systems. electrochemical properties can be calculated using self-sonstistent thermodynamic descriptions developed in this work.
Thermochemielithium ion battery --- Lithium-Ionen-Batterie --- thermische Analyse --- conversion-type electrodes --- Konversionselektroden --- CALPHAD --- thermochemistry --- thermal analysis
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The energy management of battery electric vehicle is important for maximum utilisation of the battery. This book elaborates the requirements of the energy management and defines them as mathematical optimization problem. Strategies for the development process based on dynamic programming and for driving operation based on Pontryagin’s maximum principle are presented to consider all significant influences.
Energiemanagement --- Lithium ion battery --- Optimierung --- Elektrofahrzeug --- Lithium-Ionen-Batterie --- Electric vehicle --- Energy management
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The model-aided cathode design for lithium ion batteries is presented, which enables a systematically minimization of loss processes and an increase of power and energy density. The cathode model is parametrized without values from literature by combining microstructure analysis via FIB/SEM tomography and electrochemical impedance spectroscopy and finally validated.
microstructure --- modeling --- Mikrostruktur --- Elektromobilität --- Impedanz --- impedance --- Kathode --- cathode --- lithium-ion battery --- Lithium-Ionen Batterie
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The model-aided cathode design for lithium ion batteries is presented, which enables a systematically minimization of loss processes and an increase of power and energy density. The cathode model is parametrized without values from literature by combining microstructure analysis via FIB/SEM tomography and electrochemical impedance spectroscopy and finally validated.
microstructure --- modeling --- Mikrostruktur --- Elektromobilität --- Impedanz --- impedance --- Kathode --- cathode --- lithium-ion battery --- Lithium-Ionen Batterie
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This contribution presents an analytical and a numerical model for predicting the effective thermal conductivity of porous electrode coatings as a function of microstructure parameters. Both models account for the morphological parameters and the thermal bulk materials of the constitutive cell components. The results of both models have been successfully verified against each other and validated with literature data as well as own experimental measurements.
Mechanical engineering & materials --- thermal conductivity --- thermal transport properties --- porous electrodes --- lithium-ion cell --- lithium-ion battery --- Wärmeleitfähigkeit --- thermische Transporteigenschaften --- poröse Elektroden --- Lithium-Ionen Zelle --- Lithium-Ionen Batterie
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In order to understand the current-voltage behaviour of a Lithium-Ion Battery, its impedance needs to be investigated in the low-frequency domain. This work deals with measurement, modelling and model validation in that low-frequency domain and introduces the Distribution-Function-of-Differential-Capacity (DDC) as a new tool for investigating capacity contributions of different particle sizes and particle types inside of a Lithium-Ion Battery.
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In this work the production of a thin film of lithium lanthanum titanate by tape casting for use in a lithium ion solid state battery is described. The influence of the composition of the slip on its flow properties is investigated. The layers produced are characterized both individually and in connection with a composite anode made of lithium titanate. Their suitability for use in a solid-state battery is demonstrated.
Mechanical engineering & materials --- Keramik --- Foliengießen --- Festkörperelektrolyt --- Lithium-Ionen-Batterie --- Lithium-Lanthan-Titanat --- ceramics --- tape casting --- solid electrolyte --- lithium ion battery --- lithium lanthanum titanate
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