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This book, first published in 2000, is based on the modern conceptual understanding of crystal fields. It provides readers with clear instructions and a set of computer programs for the phenomenological analysis of energy spectra of magnetic ions in solids. The text clarifies several issues that have historically produced confusion in this area, particularly the effects of covalency and ligand polarization on the energy spectra of magnetic ions. Readers are shown how to employ a hierarchy of parametrized models to extract as much information as possible from observed lanthanide and actinide spectra. This book of crystal field theory describes all of the available phenomenological models, together with the conceptual and computational tools necessary for their use. It will be of particular interest to graduate students and researchers working in the development of opto-electronic systems and magnetic materials.

Crystal field theory.

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The new edition of this landmark volume takes into account the vast amount of new spectral data on minerals, and describes a variety of applications of crystal field theory to the earth and planetary sciences. A unique perspective of the second edition is that it highlights the properties of minerals that make them compounds of interest to solid state chemists and physicists.

Crystal field theory --- Mineralogy --- Champ cristallin, Théorie du --- Minéralogie --- Crystal field theory. --- Mineralogy. --- Champ cristallin, Théorie du --- Minéralogie

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Rocks. Minerals --- fysicochemie --- Metals and their compounds --- Chemical bonds. Valence --- Crystal field theory. --- Mineralogy.

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Electron paramagnetic resonance. --- Ionic crystals. --- Transition metal ions. --- Crystal field theory.

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548.0:537 --- Crystal field theory --- General crystallography-:-Electricity. Magnetism. Electromagnetism --- Crystal field theory. --- 548.0:537 General crystallography-:-Electricity. Magnetism. Electromagnetism --- #WSCH:AAS1 --- Complex compounds --- Coordination compounds --- Transition metals