TY - BOOK ID - 50714493 TI - Crystal Structures of Compounds Containing Ions Selenite PY - 2019 SN - 3038975184 3038975176 9783038975182 PB - Basel, Switzerland : MDPI, DB - UniCat KW - Molecular and crystal structure of materials incorporating selenite anions KW - Full characterization of new selenite compounds KW - NLO properties of selenite holding materials KW - Supramolecular interactions derived from selenite containing structures KW - MOF derived from selenite containing compounds UR - https://www.unicat.be/uniCat?func=search&query=sysid:50714493 AB - The chemistry of materials containing Se oxyanions in the +4 oxidation state, such as selenite, hydrogenselenite, and oxoselenate, are of increasing interest in the research community for several reasons. First, the lone pair on the selenium atom can behave as structure-directing agent towards the formation of materials characterized by the presence of hollows or channels in their intimate structures, moreover, the weakly coordinative capability of the Se(IV) electron lone pairs could give rise to interesting supramolecular interactions, and finally, it is known that the incorporation of selenite anions can lead to non-centrosymmetric structures and, consequently, to materials displaying remarkable physicochemical properties. The most important feature is that the full comprehension of the properties of this type of materials cannot be exhaustively understood unless the complete solid state crystal structure is available. In this Special Issue, entitled "Crystal Structures of Compounds Containing Ions Selenite", a series of new selenite-containing compounds synthesized by different methodologies and fully caracterized in the solid state is reported. Moreover the fundamental role of detailed structural analysis in understanding the interactions in the solid state that are responsible for the peculiar chemical-physical properties of such materials is discussed.] ER -