TY - BOOK ID - 17131112 TI - Polar rearrangements PY - 1992 VL - 5 SN - 0198556713 0198556705 9780198556718 PB - Oxford: Oxford university press, DB - UniCat KW - Rearrangements (Chemistry) KW - Transpositions (chimie) KW - Molecular rearrangements KW - Rearrangement reactions (Chemistry) KW - 547.057 KW - Chemical reactions KW - 547.057 Organic chemistry--?.057 KW - Organic chemistry--?.057 UR - https://www.unicat.be/uniCat?func=search&query=sysid:17131112 AB - The general principles of polar rearrangements are brought together in this text, which deals with all the major rearrangements involving electron-deficient atoms or charged intermediates. Reactions involving migration to electron-deficient carbon, nitrogen, oxygen, and sulphur, and sigmatropic rearrangements involving polar species, are thus treated in a coherent and consistent manner. Clear discussions of the reaction mechanisms are followed by examples of synthetic applications, providing a concise yet comprehensive account of the nature and importance of these processes. ER -