TY - BOOK ID - 145335346 TI - Biomimetic Radical Chemistry and Applications 2021 PY - 2022 PB - Basel MDPI - Multidisciplinary Digital Publishing Institute DB - UniCat KW - Research & information: general KW - Chemistry KW - Inorganic chemistry KW - guanine KW - guanyl radical KW - tautomerism KW - guanine radical cation KW - oligonucleotides KW - DNA KW - G-quadruplex KW - time-resolved spectroscopies KW - reactive oxygen species (ROS) KW - oxidation KW - catalase mimics KW - peroxide KW - diiron-peroxo complexes KW - structure/activity KW - kinetic studies KW - biomimetic chemistry KW - cysteine KW - ketone reduction KW - free radicals KW - pulse radiolysis KW - kinetics KW - DNA oxidation KW - DNA hole transfer KW - molecular dynamics KW - quantum dynamics KW - electron transfer KW - charge transfer KW - quantum coherence KW - chemiluminescence KW - reaction mechanisms KW - singlet oxygen KW - reactive oxygen species KW - light emission KW - crosslink KW - dimerization KW - protein oxidation KW - radicals KW - di-tyrosine KW - di-tryptophan KW - disulfides KW - thiols KW - aggregation KW - proteomics KW - mass spectrometry KW - collagen KW - riboflavin KW - hyaluronic acid KW - EPR spectroscopy KW - keratoconus KW - STEM KW - DNA biosensor KW - chemical nucleases KW - DNA-drug interaction KW - copper complexes KW - metallodrugs KW - MEP pathway KW - antibiotics KW - IspH KW - LytB KW - [4Fe-4S] cluster KW - reductive dehydroxylation KW - bioorganometallic intermediate KW - inhibitors KW - methionine KW - neighboring group effect KW - hydroxyl radical KW - triplet state of carboxybenzophenone KW - one-electron oxidants KW - laser flash photolysis KW - peptides KW - proteins KW - guanine KW - guanyl radical KW - tautomerism KW - guanine radical cation KW - oligonucleotides KW - DNA KW - G-quadruplex KW - time-resolved spectroscopies KW - reactive oxygen species (ROS) KW - oxidation KW - catalase mimics KW - peroxide KW - diiron-peroxo complexes KW - structure/activity KW - kinetic studies KW - biomimetic chemistry KW - cysteine KW - ketone reduction KW - free radicals KW - pulse radiolysis KW - kinetics KW - DNA oxidation KW - DNA hole transfer KW - molecular dynamics KW - quantum dynamics KW - electron transfer KW - charge transfer KW - quantum coherence KW - chemiluminescence KW - reaction mechanisms KW - singlet oxygen KW - reactive oxygen species KW - light emission KW - crosslink KW - dimerization KW - protein oxidation KW - radicals KW - di-tyrosine KW - di-tryptophan KW - disulfides KW - thiols KW - aggregation KW - proteomics KW - mass spectrometry KW - collagen KW - riboflavin KW - hyaluronic acid KW - EPR spectroscopy KW - keratoconus KW - STEM KW - DNA biosensor KW - chemical nucleases KW - DNA-drug interaction KW - copper complexes KW - metallodrugs KW - MEP pathway KW - antibiotics KW - IspH KW - LytB KW - [4Fe-4S] cluster KW - reductive dehydroxylation KW - bioorganometallic intermediate KW - inhibitors KW - methionine KW - neighboring group effect KW - hydroxyl radical KW - triplet state of carboxybenzophenone KW - one-electron oxidants KW - laser flash photolysis KW - peptides KW - proteins UR - https://www.unicat.be/uniCat?func=search&query=sysid:145335346 AB - The high importance of free radical chemistry for a variety of biological events, including ageing and inflammation, has attracted considerable interest in understanding the related mechanistic steps at the molecular level. Modelling the free radical chemical reactivity of biological systems is an important research area. When studying free-radical-based chemical mechanisms, biomimetic chemistry and the design of established biomimetic models come into play to perform experiments in a controlled environment, suitably designed to be a similar as possible to cellular conditions. This Special Issue provides readers with a wide overview of biomimetic radical chemistry, where molecular mechanisms have been defined and molecular libraries of products are developed to be used as traces for the discoveries of some relevant biological processes. Several subjects are presented, with five articles and five reviews written by specialists in the fields of DNA, proteins, lipids, biotechnological applications and bioinspired synthesis, with “free radicals” as the common denominator. ER -