TY - BOOK ID - 135754687 TI - Coordination Chemistry of Silicon PY - 2019 PB - MDPI - Multidisciplinary Digital Publishing Institute DB - UniCat KW - cluster KW - molecular orbital analysis KW - bond activation KW - X-ray diffraction KW - silsesquioxanes KW - digermacyclobutadiene KW - intermetallic bond KW - germanium KW - computational chemistry KW - ?-electron systems KW - isocyanide KW - X-ray crystallography KW - cyclic organopolysilane KW - disilene KW - ruthenium KW - platinum KW - DFT KW - Photostability KW - silicon surfaces KW - stereochemistry KW - palladium KW - distorted coordination KW -
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Si NMR spectroscopy KW - organosilicon KW - disilanylene polymer KW - Si–Cl activation KW - adsorption KW - AIM KW - siliconoid KW - nanoparticle KW - disiloxane tetrols KW - germylene KW - hydrogen bonding KW - TiO
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KW - dehydrogenative alkoxylation KW - siloxanes KW - 2-silylpyrrolidines KW - bonding analysis KW - ?-chloro-?-hydrooligosilane KW - hydrido complex KW - oxidative addition KW - photoreaction KW - template KW - surface modification KW - titanium KW - bromosilylenes KW - host-guest chemistry KW - hydrogen bonds KW - salt-free KW -
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-heterocyclic carbines KW - silicon cluster KW - condensation KW - silyliumylidenes KW - Baird’s rule KW -
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-heterocyclic carbenes KW - reductant KW - main group coordination chemistry KW - molecular cage KW - subvalent compounds KW - isomerization KW - silanetriols KW - germathioacid chloride KW - dehydrobromination KW -
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-heterocyclic carbene KW - mechanistic insights KW - ligand-exchange reaction KW - bridging silylene ligand KW - dye-sensitized solar cell KW - silylene KW - computation KW - functionalization KW - silicon KW - digermene KW -
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-Heterocyclic tetrylene KW - density functional theory KW - primary silane KW - small molecule activation KW - excited state aromaticity KW - germanethione KW - supramolecular chemistry UR - https://www.unicat.be/uniCat?func=search&query=sysid:135754687 AB - The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist's viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds. ER -