TY - BOOK ID - 134312784 TI - Transition Metal Catalyzed Cross-Coupling Reactions PY - 2021 PB - Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute DB - UniCat KW - Technology: general issues KW - Suzuki–Miyaura cross-couplings KW - C(sp3) –C(sp2) KW - alkylboron reagents KW - metal catalysis KW - alpha-helix KW - anode KW - CH-activation KW - cross-coupling KW - electrosynthesis KW - oligoarene KW - peptidomimetics KW - phenol KW - protein-protein interactions KW - triflate KW - thiosemicarbazone KW - metal complex KW - transition metal catalysis KW - cross-coupling reaction KW - Heck reaction KW - Suzuki reaction KW - Sonogashira reaction KW - Kumada reaction KW - Buchwald–Hartwig reaction KW - deposited catalysts KW - palladium KW - functional amides KW - alkynyl ketone synthesis KW - n/a KW - Suzuki-Miyaura cross-couplings KW - C(sp3) -C(sp2) KW - Buchwald-Hartwig reaction UR - https://www.unicat.be/uniCat?func=search&query=sysid:134312784 AB - Transition metal-catalyzed cross-coupling reactions have proved to be powerful tools for carbon–carbon as well as carbon–heteroatom bond formation in the development of synthetic methodologies for applications ranging from pharmaceuticals to materials. This book, consisting of an editorial, two reviews and two articles, focuses on recent promising research and novel trends in the field of cross-coupling reactions, employing a range of different catalysts. A review by Kostas and Steele provides a survey of the research in the area of cross-coupling catalytic reactions with transition metal complexes based on the thiosemicarbazone unit and a discussion of the prospects for future developments. Another review by Polychronopoulou, Shaya and co-authors describes the progress made over the 21st century concerning the utilization of C(sp3)–organoboranes as partners in metal-catalyzed C(sp3)–C(sp2) cross-couplings, such as B-alkyl Suzuki–Miyaura reactions. The article by Waldvogel, Breinbauer and co-authors demonstrates for the first time the synthetic potential of combining the electro-oxidative dehydrogenative cross coupling of ortho-substituted phenols with Pd-catalyzed cross-coupling reactions. In the second article, Štĕpnička and co-workers describe the preparation of palladium catalysts deposited over silica gel-bearing composite amide-donor functional moieties on the surface, which were evaluated in the Sonogashira-type cross-coupling of acyl chlorides with terminal alkynes. ER -